Compared to uncross-linked products cross-linked products - cross-linked with cross-linker DCP is generally greater than that of uncross-linked specimens. Even when the DCP content of cross-linked polyethylene is only 0.5 wt%, the DC breakdown fi eld ...

 
Aug 17, 1999 · The effect of cross-linking on the secondary structure of crystalline HSA has been studied by FTIR spectroscopy. The second derivative of FTIR spectra of uncross-linked crystals, lCLPC–HSA and hCLPC–HSA were compared in the amide I region after area normalization and curve fitting (Fig. 3). . Boldt funeral faribault mn

Compared to uncross-linked products, cross-linked nail enhancements are _____ to solvents. More resistant . All nail adhesives and wraps are based on ... When your clients fingertips are soaking in a container of acetone to aid the removal of a nail enhancement product, it is recommended that you cover the container with _____. A clean terry ...The opening cross is NASDAQ’s current technique for setting opening prices. Learn about NASDAQ's opening and closing cross. Advertisement If you've ever traded stocks, you know ...The common feature of non-cross-linked hyaluronic acid nano-needles is that they penetrate the skin and dissolve rapidly, and the non-cross-linked hyaluronic acid will migrate under the skin, so it is difficult to maintain the long-term expansion effect ...A substantial amount of uncross-linked telopeptide structures was also found. Previous studies, where direct chemical cross-link analyses have been used to assess the maturity of cross-linking, have inferred that bone contains more divalently than trivalently cross-linked C-telopeptides.In the case of cross-linked casein micelles, it is generally acknowledged that mTGase catalyses the formation of intra-molecular bonds between the caseins rather than the cross-linking between the micelles (Fig. 2).This notion is supported by particle size measurements by dynamic light scattering since the cross-linked casein had slight …The opening cross is NASDAQ’s current technique for setting opening prices. Learn about NASDAQ's opening and closing cross. Advertisement If you've ever traded stocks, you know ...Jan 1, 2012 · Our results show that the microhardness and elastic modulus for cross-linked chitosan films are higher than the uncross-linked films. However, the cross-linked chitosan films show increased brittleness when compared to uncross-linked films. By increasing the load magnitude, the microhardness increases for both uncross-linked and cross-linked ... A cross Linker. A Oligomers. 32 Q Liquid and powder systems use_that gather energy from the heat of the room or hand while UV curing products use photo initiators that derive their extra energy from exposure to UV. ... Compared to uncross linked products cross linked nail enhancements. Take less time to remove in acetoneCreating a URL link is an essential part of any digital marketing strategy. Whether you’re linking to a page on your website, an article you wrote, or a product you’re selling, hav...Cross-linking by EDC-NHS route results in better stability in comparison to cross-linking methods, such as dehydrothermal cross-linking [75,[83] [84] [85]. However, a comparative study of cross ...To add cross-sell, open products edit form, navigate to ‘Linked Products’ tab and start typing item’s name (at least 3 characters). You will be able to see matches in drop-down and select the most suitable one (s). To add a few cross-sells, repeat the process the necessary amount of time. WooCommerce Cross Sell Product in the Admin.Thermal properties of cross-linked and uncross-linked low-density polyethylene (LDPE)/Fischer–Tropsch wax blends were investigated in this paper. For cross-linked blends, the gel content was determined. It was observed that the gel content increases with an increase in DCP concentration. The degree of crystallinity decreased with an increase ...DOI: 10.1016/j.jmbbm.2011.08.006 Corpus ID: 42702849; Nano and micro mechanical properties of uncross-linked and cross-linked chitosan films. @article{Aryaei2012NanoAM, title={Nano and micro mechanical properties of uncross-linked and cross-linked chitosan films.}, author={Ashkan Aryaei and Ahalapitiya H. …For the cross-linked PCS samples, several additional weak peaks at 1456 cm −1 and 1602 cm −1 are observed in the spectra compared to that of the uncross-linked sample which originate from the bending vibration of the C˭C bond in the aromatic ring of DVB.The DSC curves of all the systems, pure LLDPE, cross-linked LLDPE and uncross-linked and cross-linked blends, show beside the main exothermic peak another very small peak at about 70°C (Fig. 2, Fig. 4 — peak at about 70°C is obvious and reproducible in original curves, but is not so obvious in reproduction). The main peak is …Relative to the soluble protein, crystalline forms induce and sustain over almost a 6-month study a 6- to 10-fold increase in antibody titer for highly cross-linked …The best-known examples are cross-linked polyethylene (PE-X), which has become a viable alternative for PVC in pipes, and cross-linked polyamide, which is commonly used in the automotive sector. There is also a wide range of material systems, which cure through cross-linking. These include, for example, thermosetting materials …an adhesive. a nail polish base coat is a type of. primer. which of the following is not a basic type of primer? dual acid. a substance that can cause visible and possibly permanent skin or eye damage is. a corrosive. a corrosive acid-based primer can cause painful burns and _____________ to soft tissue and eyes. scars.With the assumptions that the cross-linked products had a spherical shape and the R g values approximated the molecular radii, the polymer volumes after 95% cross-linking were calculated to be between just 33% and 39% of the original dendrimer volume. Given a less than 10% mass reduction in the RCM reaction, this size reduction indicates a ...The final PU product was dried for a week to completely remove any remaining DMF. ... compared to uncross-linked soft segment copolymer. Although some of the hard segments were cross-linked by the different contents of dextrin, the soft segment was not bound to dextrin, and thus, permitted an unrestricted movement of the …The SEM image of the uncross-linked and DHT cross-linked gelatin scaffolds are depicted in Figure 1. The gelatin nanofibers presented randomly oriented morphology and smooth surfaces. The distributions of the fiber diameter for uncross-linked gelatin scaffolds are observed to be on average 675±30 nm, and the DHT cross-linked gelatin scaffolds ...Thermal properties of cross-linked and uncross-linked low-density polyethylene (LDPE)/Fischer–Tropsch wax blends were investigated in this paper. For cross-linked blends, the gel content was determined. It was observed that the gel content increases with an increase in DCP concentration. The degree of crystallinity decreased …The DSC curves of all the systems, pure LLDPE, cross-linked LLDPE and uncross-linked and cross-linked blends, show beside the main exothermic peak another very small peak at about 70°C (Fig. 2, Fig. 4 — peak at about 70°C is obvious and reproducible in original curves, but is not so obvious in reproduction). The main peak is …Hyper Cross-linked polymers (HCPs) are class of porous materials that have been intensively used in the past few years. The HCP material is in most cases synthesized by Friedel Craft reactions. The HCP material is synthesized by the following three methods: Post crosslinking of polymer precursors, direct single step poly-condensation reaction of functional monomers, and Crosslinking by ...Mar 30, 2012 · Rationale: Chemical cross-linking in combination with a mass spectrometric analysis of the created cross-linked products is an area of growing interest for deriving low-resolution structural information of proteins and protein complexes. One of the greatest challenges is the complexity of the created cross-linking mixtures, which can be met by ... Chemistry. Chemistry questions and answers. An important application of Equation 10.5.15 is the evaluation of M.; P.J. Flory, N. Rabjohn, and M.C. Shaffer measured the tensile force required for 100% elongation of synthetic rubber with variable cross-linking at 25°C. The molecular weight of the uncross-linked polymer was 225,000, its density ... Our results show that the microhardness and elastic modulus for cross-linked chitosan films are higher than the uncross-linked films. However, the cross-linked chitosan films show increased brittleness when compared to uncross-linked films. By increasing the load magnitude, the microhardness increases for both uncross-linked and cross-linked ...Advanced Physics questions and answers. An important application of Equation 10.5.15 is the evaluation of Mr; P.J. Flory, N. Rabjohn and M.C. Shaffer measured the tensile force required for 100% elongation of synthetic rubber with variable cross-linking at 25°C. The molecular weight of the uncross-linked polymer was 225,000, its density was 0. ...Quartz is a guide to the new global economy for people in business who are excited by change. We cover business, economics, markets, finance, technology, science, design, and fashi...To compare type b and c cross-links, fully cross-linked dendrons 5a, 5b, and 5c were synthesized through different methods (Figure 3c). ... With the assumptions that the cross-linked products had a spherical shape and the R g values approximated the molecular radii, the polymer volumes after 95% cross-linking were calculated to be …Download scientific diagram | Swelling degree of the uncross-linked and cross-linked PVA and PVA/Zr-MOFs membranes in water and water/isopropanol (12/88 and 30/70 wt%) mixtures. from publication ...The opening cross is NASDAQ’s current technique for setting opening prices. Learn about NASDAQ's opening and closing cross. Advertisement If you've ever traded stocks, you know ...With the efficient cross-linking abilities and the flexible regulation abilities to the performances of cross-linked products, the multi-functional aliphatic epoxides were once widely used to cross-link the collagen-based materials in the last century. In present work, the multi-functional epoxides were used to construct and cross-link collagen …of cross-linking suggested that calmodulin was bound at the calmodulin binding domain of MLCK. Preparation of the 110-kDa Product-Separation of the products of the cross-linking reaction was attempted in order to isolate the 110-kDa product from uncross-linked MLCK FIG. 1. Cross-linking of calmodulin and MLCK with DCC.The Cross Product (TCP) | 2,174 followers on LinkedIn. AI and 3D LIDAR for infrastructures | The Cross Product offers railway and highway softwares performing inspections, inventories, reverse ...Our results show that the microhardness and elastic modulus for cross-linked chitosan films are higher than the uncross-linked films. However, the cross-linked chitosan films show increased brittleness when compared to uncross-linked films. By increasing the load magnitude, the microhardness increases for both uncross-linked and cross-linked ...Maxium Barrault wanted to implement Jerry Seinfeld's productivity secret of forming a chain by crossing off the calendar every day, but apps like Habit Streak Plan weren't doing it...Cross-linked nanofiber films had a water contact angle change rate of 24.2%-40% in 10 s, which was much lower than that of uncross-linked nanofiber (50.8%). This may be because the polar groups on the zein/PVA molecular chain were consumed during the cross-linking reaction, which reduced the hydrophilicity of the nanofibers.We also synthesize an uncross-linked poly(n-butyl 4-styrenesulfonate) as a control sample for comparison with a cross-linked polymer. The conductivities of the CL-sSA membrane with the high f sSA are measured by impedance spectroscopy, and the conductivities are compared with those of conventional PEMs with a low f sSA .Relative to the soluble protein, crystalline forms induce and sustain over almost a 6-month study a 6- to 10-fold increase in antibody titer for highly cross-linked …The cross-linking structure of the Ethylene-propylene-diene monomer (EPDM) is made up of a number of cross-linking types, including carbon atoms from the main chain or monomer and ether crosslinks formed during degradation. Through molecular dynamic simulations, the contribution of each type of cross-linked structure to the …This behavior was observed for microparticles uncross-linked and cross-linked with genipin, indicating a tendency of slower release as chitosan concentration rises from 1.5 to 2.0 %. For microparticles containing 1.0 and 1.5 % of chitosan, an approximate fourfold decrease of k BL was observed in the comparison of spheres uncross-linked …Purpose: To evaluate the 36 months changes in posterior corneal surface parameters in keratoconic eyes after accelerated corneal cross-linking and to compare the data with uncross-linked progressive and non-progressive keratoconic eyes. Methods: Thirty five cross-linked, 30 uncross-linked progressive, and 30 uncross-linked non-progressive …As expected, the surface morphology and fiber diameter were observed to remain relatively unchanged when compared to uncross-linked electrospun gelatin scaffolds. The SEM image of the uncross-linked and DHT cross-linked gelatin scaffolds are depicted in Figure 1. The gelatin nanofibers presented randomly oriented morphology and smooth surfaces.The efficacy results within 3 months of one single treatment are more impressive than our general understanding of non-cross-linked HA injection, whereas …cytes (NHEK) on the cross-linked and uncross-linked fibrinogen/polycaprolactone (Fbg/PCL) nanofibers to determine a suitable scaffold for skin tissue engineering.May 23, 2022 · The common feature of non-cross-linked hyaluronic acid nano-needles is that they penetrate the skin and dissolve rapidly, and the non-cross-linked hyaluronic acid will migrate under the skin, so it is difficult to maintain the long-term expansion effect in a fixed position. In order to achieve the relatively long-term antiwrinkle effect, a kind of cross-linked and non-cross-linked compound ... Thermal stability of cross-linked and uncross-linked LLDPE was characterized in terms of the temperatures of 5 and 10% degradation and also in terms of the temperature at the inflexion point. The results are summarized in Table 3. Our results show that cross-linking via gamma-irradiation slightly improves the thermal stability of … The results were compared with calculated values obtained previously4 on the basis of the theory. ... the uncross-linked polymer, Tg is cross-linked polymer and n The uncross-linked cellulose hydrogels had a swelling ratio of 325%, while the swelling ratio of the cross-linked hydrogels could achieve ~ 900%. With increasing …Compared to uncross-linked products, cross-linked nail enhancements: are more resistant to solvents. All nail adhesives and wraps are based on: cyanoacrylates.Compared with uncross-linked films, the mechanical properties, barrier properties and water resistance of the cross-linked films were significantly improved. When the concentration of CA was 5 wt% (W/W, on a dry basis of the weight of OVT and CS), the most significant improvement in film performance was obtained.The common feature of non-cross-linked hyaluronic acid nano-needles is that they penetrate the skin and dissolve rapidly, and the non-cross-linked hyaluronic acid will migrate under the skin, so it is difficult to maintain the long-term expansion effect in a fixed position. In order to achieve the relatively long-term antiwrinkle effect, a kind of cross-linked and non-cross-linked compound ...Cross-linked thermoplastics represent an important class of materials for numerous applications such as heat-shrinkable tubing, rotational molded parts, and polyolefin foams. By cross-linking olefins, their mechanical performance can be significantly enhanced. This chapter covers the three main methods for the cross-linking of thermoplastics ...Adjustment of the β-casein content was achieved by blending uncross-linked or cross-linked β-casein poor solution with uncross-linked β-casein rich solution in ratios of 70:30, 80:20, 90:10, or 100:0, with 90:10 roughly corresponding to the status of the original skim milk (this was estimated from the weight of the achieved powders).Here, we describe the isolation and characterisation of carboxy-terminal telopeptide structures of type I collagen from human mineralised bone. Analysis of the collagen cross-links within the purified structures indicated the presence of trivalent ICTP structures, divalently cross-linked peptides and uncross-linked telopeptide chains.To add cross-sell, open products edit form, navigate to ‘Linked Products’ tab and start typing item’s name (at least 3 characters). You will be able to see matches in drop-down and select the most suitable one (s). To add a few cross-sells, repeat the process the necessary amount of time. WooCommerce Cross Sell Product in the Admin.Study with Quizlet and memorize flashcards containing terms like When should you remove an artificial nail?, Methyl methacrylate monomer (MMA):, Compared to uncross-linked products, cross-linked products: and more. a subunit in the cross-linked product. Cross-linked Go can be ADP-ribosylated by pertussis toxin. This ADP- ribosylation is inhibited by GTPrS with a concentra- tion dependence that is indistinguishable from that of the control, uncross-linked Go. These two kinds of ex- periments indicate that a, is able to change its confor- mation even though ... Are you in need of a Windows 10 product key to activate your operating system? Whether you’ve just built a new computer or are looking to upgrade from an older version of Windows, ...Krupa and Luyt (2000), from their studies on uncross-and cross-linked wax/LLDPE blends concluded There is a shift with the addition of filler material on paraffin wax due to macroscopic ...Increase in Young's modulus as well as the maximum stress is observed in the cross-linked system compared with the uncross-linked chitosan system and CS/HAP nanocomposites. The stress–strain behavior of chitosan system and a system with different percentages of HAP (10%, 20% & 30%) are shown in Fig. 2 (b).an adhesive. a nail polish base coat is a type of. primer. which of the following is not a basic type of primer? dual acid. a substance that can cause visible and possibly permanent …cytes (NHEK) on the cross-linked and uncross-linked fibrinogen/polycaprolactone (Fbg/PCL) nanofibers to determine a suitable scaffold for skin tissue engineering.The process of cross-linking makes the hyaluronic acid resistant to enzymatic breakdown and thereby it is able to remain in the body for months after filling. Longer-lasting effect. Cross-linked hyaluronic acid is longer-lasting and more stable compared to non-cross-linked or natural hyaluronic acid. So it is a better option for …Jun 24, 2014 · Biodegradable blends of potato starch and polyvinyl alcohol were prepared by solution casting method. Citric acid was employed to introduce the plasticizing effect into the starch materials. Glutaraldehyde as cross-linker was used to enhance the properties of the blend films. Cross-linking is a common method to improve the strength and stability of starch products. The effects of citric acid ... When the cross-linking was complete, the thickness and grammage of the coatings were increased when compared with their non-cross-linked counterparts. The weight gain observed after the cross-linking is due to the accumulation of the CA attached by esterification into the hydroxyl groups in the nanocellulose fibers (De Cuadro et al. …In today’s digital age, where technology plays a vital role in our daily lives, the need for seamless integration between devices has become increasingly important. One such integr...Mar 15, 2023 · The STPP cross-linked coacervates were used as wall materials for Sichuan pepper essential oil (SPEO) encapsulation with encapsulation efficiency of 87.25 %. Compared with uncross-linked microcapsules, cross-linked microcapsules showed higher SPEO retention at high temperature, different pH, and high ionic concentration. Maize bran is a by-product obtained after the milling of maize kernels and separated as by-product. ... The results depicted that AXs showed the higher antioxidant potential as compared to their cross-linked structure. ... up to 61–64% and reported that cross- and uncross-linked AXs showed the antioxidant potential including 16.83 ± 0.83 …Thermal, mechanical and dielectric properties of the films are systematically compared. Due to the presence of F atoms and cross-linked structure in polymer chains, these polymeric films exhibit remarkable dielectric properties with the lowest dielectric constant < 2.4 and dissipation factor < 0.003 at frequency from 100 Hz to 1 MHz. cytes (NHEK) on the cross-linked and uncross-linked fibrinogen/polycaprolactone (Fbg/PCL) nanofibers to determine a suitable scaffold for skin tissue engineering. However, for the PSA film cross-linked with SAC-100, it would be expected that the intensity of the OH stretching vibration peak at 3285 cm −1 would be reduced and even disappeared (curve b), when compared with uncross-linked adhesive (curve a), indicating the reaction between the curing agent SAC-100 with carboxylated PSA, as …an adhesive. a nail polish base coat is a type of. primer. which of the following is not a basic type of primer? dual acid. a substance that can cause visible and possibly permanent …Biodegradable blends of potato starch and polyvinyl alcohol were prepared by solution casting method. Citric acid was employed to introduce the plasticizing effect into the starch materials. Glutaraldehyde as cross-linker was used to enhance the properties of the blend films. Cross-linking is a common method to improve the strength and stability of starch products. The effects of citric acid ...For pure CS film, TPP cross-linked film significantly improved the elastic modulus compared to the noncross-linked one, whose elastic modulus values were close to the reported values for human ...Need a cross platform mobile app development company in Poland? Read reviews & compare projects by leading cross platform app developers. Find a company today! Development Most Pop...Are you in need of a Windows 10 product key to activate your operating system? Whether you’ve just built a new computer or are looking to upgrade from an older version of Windows, ...SEM microphotographs of the chitosan microspheres cross-linked with d,l-glyceraldehyde and glutaraldehyde are compared in Figure 6. No visible changes in the morphological aspect of the spray-dried chitosan microspheres due to the chemical cross-linking were observed, compared to the uncross-linked microspheres already shown …May 26, 2022 · The uncross-linked cellulose hydrogels (B0) contained water of 90.8%, while with the incorporation of borax, the water content contained in the cross-linked B1 hydrogels increased to 92.6%. Low cell viability is present in the glutaraldehyde cross-linked hydrogel, this might be because it acts as a chemical cross-linking agent and induces cytotoxicity. The freeze–thaw and genipin cross-linked hydrogels exhibit greater cell viability in comparison with uncross-linked hydrogels and TCPS (Tissue Culture Polystyrene) control. [9]. 3 ...

The opening cross is NASDAQ’s current technique for setting opening prices. Learn about NASDAQ's opening and closing cross. Advertisement If you've ever traded stocks, you know .... Kaiser clairemont mesa pharmacy

compared to uncross-linked products cross-linked products

Here, we describe the isolation and characterisation of carboxy-terminal telopeptide structures of type I collagen from human mineralised bone. Analysis of the collagen cross-links within the purified structures indicated the presence of trivalent ICTP structures, divalently cross-linked peptides and uncross-linked telopeptide chains.Purpose To evaluate the 36 months changes in posterior corneal surface parameters in keratoconic eyes after accelerated corneal cross-linking and to compare the data with uncross-linked progressive and non-progressive keratoconic eyes. Methods Thirty five cross-linked, 30 uncross-linked progressive, and 30 uncross-linked non-progressive keratoconic eyes were included. Maximum keratometry (Kmax ...The aim of this study was an investigation on the proliferation rate of normal human epidermal keratinocytes (NHEK) on the cross-linked and uncross-linked fibrinogen/polycaprolactone (Fbg/PCL) nanofibers to determine a suitable scaffold for skin tissue engineering. Nanofibrous scaffolds were prepared by electrospinning of different weight ratios of Fbg to PCL and were analyzed as morphology ...FRAM does offer an oil filter cross reference chart, which can be found via its search engine on its website, as of 2015. The chart showcases competitors, such as Motorcraft, with ...cross-linked with cross-linker DCP is generally greater than that of uncross-linked specimens. Even when the DCP content of cross-linked polyethylene is only 0.5 wt%, the DC breakdown fi eld ...The divergent nature of chemically and physically cross-linked products tailors them to specific applications. Chemically cross-linked foams feature fine-celled structures, epitomizing toughness and longevity, as seen in materials like cross-linked polyethylene foam and foam rubber. While their rough exterior may lack aesthetic …Another effective approach toward continually reprocessable cross-linked polymers is to control the reversible transformation between a cross-linked and …The TGA curves of uncross-linked blends, analyzed under nitrogen atmosphere, are shown in Fig. 3.The temperatures of 5 and 10% decomposition for both uncross-linked and cross-linked blends are summarized in Table 2.These temperatures decrease with increasing wax content for uncross-linked blends, being somewhere …Sodium caseinate is widely used as techno-functional ingredient in food processing. However, no studies are currently available on applications of enzymatically cross-linked sodium caseinate although such a modification might have a potential to improve its techno-functional properties and thus reduce the amount of protein necessary to achieve the desired product properties. In the present ...May 23, 2022 · The common feature of non-cross-linked hyaluronic acid nano-needles is that they penetrate the skin and dissolve rapidly, and the non-cross-linked hyaluronic acid will migrate under the skin, so ... Variation of microhardness (A) and elastic modulus (B) versus applied load for uncross-linked and cross-linked chitosan films. Download : Download high-res image (143KB) Download : Download full-size image; Fig. 8. Comparison between the elastic modulus which was obtained in uncross-linked and cross-linked chitosan films using two different ...A cross-linking reagent is required to improve mechanical strength and degradation properties of biopolymers for tissue engineering. To find the optimal preparative method, we prepared diverse genipin-cross-linked chitosan/collagen scaffolds using different genipin concentrations and various cross-linking temperatures and cross …The common feature of non-cross-linked hyaluronic acid nano-needles is that they penetrate the skin and dissolve rapidly, and the non-cross-linked hyaluronic acid will migrate under the skin, so it is difficult to maintain the long-term expansion effect ... Download scientific diagram | -Comparison between the elastic modulus which was obtained in uncross-linked and cross-linked chitosan films using two different methods. from publication: Nano and ... 2.3.. Viscoelasticity measurementsUncross-linked and cross-linked starch–pectin samples (5%, w/v) were prepared in 20 ml sealed screw-capped flasks with deionised water using a motorised stirrer.For gelatinisation of the uncross-linked blends, the polysaccharide dispersions were heated to ∼80 °C for 20 min under continuous …Yet, the cross-linked nanocomposites exhibited decrements of 6.38–39.53%. This indicates that the gas permeability of PBS was more effectively depressed by the addition of OMLS than by the cross ...Compared with cross-linked AEMs, uncross-linked membranes with similar ion exchange capacities showed a much higher water uptake and swelling degree. Cross-linked membranes showed vastly improved alkaline stability, oxidation stability and mechanical properties compared with uncross-linked membranes due to the effective …In a multi-center, patient-blind, RCT of 660 patients with knee OA, 3 different viscosupplements were used: High molecular weight, chemically cross-linked, non-animal derived HA (hylan) High ...Before having surgery, tell your doctor or dentist about all the products you use (including prescription drugs, nonprescription drugs, and herbal products). During pregnancy, this medication should be used only when clearly needed. Discuss the risks and benefits with your doctor. It is unknown if this drug passes into breast milk.The common feature of non-cross-linked hyaluronic acid nano-needles is that they penetrate the skin and dissolve rapidly, and the non-cross-linked hyaluronic acid will migrate under the skin, so ....

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